Product ID:TROPICAL GREEN ENAMEL, 101-080
MSDS Date:11/14/1988
FSC:8010
NIIN:00N020401
MSDS Number: BLRMC

D J SIMPSON COMPANY

111 SOUTH MAPLE AVE
SOUTH SAN FRANCISCO, CA 94080
US

Emergency Phone: 415-873-5990

Info Phone: 415-873-5990

Cage: HO887

SIMPSON D J CO INC

2265 SOUTH SAN FRANCISCO, CA 94080-6303 US

Telephone: 415-873-5990

Cage: 33244

STODDARD SOLVENT

CAS: 8052-41-3

RTECS: WJ8925000

Fraction By Weight: 20%

OSHA PEL 500 PPM

ACGIH TLV: 100 PPM; 9293

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

Fraction By Weight: 20 - 25%

OSHA PEL 15 MG/M3 TDUST

ACGIH TLV: 10 MG/M3 TDUST; 9293

LEAD SULFOCHROME; (LEAD CHROMATE LEAD SULFATE)-62%LEAD AS

CAS: 1344-37-2

Fraction By Weight: 0.90%

OSHA PEL 0.5 MG(CR)/M3

ACGIH TLV: 0.5 MG(CR)/M3

OR BURNING SENSATION. CRACKING & DEFATTING ACTION

RTECS: 9999999ZZ

LIQ TRASFER. EMPTY CNTNRS MAY STILL

RTECS: 9999999ZZ

COMPOUNDS, ETHANOL/METHANOL. LEAD CHROMATE LEAD

RTECS: 9999999ZZ

CHROMIUM AS CR VI.

RTECS: 9999999ZZ

LD50 LC50 Mixture:NONE SPECIFIED BY MANUFACTURER.
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO
Health Hazards Acute and Chronic:INHAL: ANESTH. IRRIT OF RESP TRACT
W/HDCH, NAUS, DIZZ, UNCONC/COMA. EXCESSIVE CHRONIC EXPOS TO LEAD
COMPOUND MAY CAUSE A METALLIC TASTE IN MOUTH, LOSS OF APPETITE,
CONSTIPATION, ABDOM CRAMPS, SLEEPLES SNESS/WEAKNESS. LEAD COMPOUNDS
,WHEN INGEST HAVE A CUMULATIVE (SEE EFTS OF OVEREXP)
Explanation of Carcinogenicity:LEAD CHROMATE: CLASS 1 (NTP/IARC); LEAD:
CLASS 2B (IARC).
Effects of Overexposure:HLTH HAZ: TOXIC EFT, WHEN AMOUNTS INGESTED
EXCEED THE LEVEL WHICH THE BODY CAN NORMALLY ELIMINATE. INHAL:
DIZZ, NAU, HDCH, IRRIT OF RESP TRACT, VOMIT, UNCONC/EVEN
ASPHIXIATION. PRLNG & RPTD OCCUP OVER EXP TO THE SOLVS MAY LEAD TO
PERM BRAIN& NERVOUS SYSTEM DAM. SKIN: IRRIT, DRYING/CRACKING &
DEFATTING. (SEE SUPP DATA)
Medical Cond Aggravated by Exposure:PRE-EXISTING HEART, LIVER, KIDNEY,
LUNG, SKIN DISORDERS.

First Aid:INHAL: REMOVE FROM EXPOSURE, RESTORE BREATHING, CONSULT MD.
EYE: FLUSH WITH LARGE AMOUNTS OF WATER FOR 15 MINUTES WITH LIDS
OPEN. CONSULT MD IMMEDIATELY. SKIN: WASH WITH SOAP AND WATER,
REMOVE CONTAMI NATED CLOTHING. INGEST: DO NOT INDUCE VOMITING.
DRINK ONE OR TWO GLASSES OF WATER TO DILUTE. SEE MD IMMEDIATELY.

Flash Point Method:TCC
Flash Point:106F,41C
Lower Limits:1%
Extinguishing Media:FOAM, CO2, DRY CHEMICAL, WATER FOG.
Fire Fighting Procedures:WEAR NIOSH/MSHA SCBA & FULL PROT EQUIP . FIGHT
AS VOLATILE LIQ FIRE. USE WATER TO COOL FIRE-EXPOSED CNTNRS. AVOID
SPREADING FIRE W/COOLING H2O.(SUP DATA)
Unusual Fire/Explosion Hazard:COLSED CNTNRS MAY EXPLED WHEN EXPOSED TO
EXTREME HEAT. VAPS MAY BE MOVED BY VENT/TRAVEL ON GROUND TO DISTANT
SOURCES OF IGNIT.ISOLATE FROM ALL SOURCES (SUP DATA

Spill Release Procedures:VENTILATE AREA. REMOVE ALL SOURCES OF
IGNITION. CONTAIN AND REMOVE WITH INERT ABSORBENT AND NON-SPARKING
TOOLS, WEAR PROTECTIVE EQUIPMENT DURING CLEANUP. CONTAIN LIQUID TO
PREVENT CONTAMINTION OR SOIL OR GROUND WATER.
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:KEEP CLOSURE TIGHT & CNTNR IN UPRIGHT
POSITION. STORE AWAY FROM HEAT/OTHER SOURCES IGNITION. CNTNRS MUST
BE GROUNDED AND/OR BONDED DURING (SEE ING 5)
Other Precautions:AVOID PRLNGED BRTHG VAPS, SKIN/EYE CONT. IN CASE OF
CONT WASH THOROUGHLY W/H2O. DO NOT TAKE INTERNALLY. INGEST: MAY
RESULT IN TOX LEVELS OF LEAD IN BODY. PRODUCT SUBJECT TO REG OF
CALIF PROP 65. COCNT AINS <1% BY WT ZIRCONIUM (SEE ING 6)

Respiratory Protection:NIOSH/MSHA APPROVED CHEMICAL MECHANICAL FILTER
RESPIRATOR.
Ventilation:REQUIRED, 200 CFM MINIMUM.
Protective Gloves:CHEMICALLY RESISTANT PLASTIC OR RUBBER.
Eye Protection:CHEMICAL WORKERS GOGGLES .
Other Protective Equipment:EYE WASH AND SAFETY SHOWERS IN WORK AREA ARE
RECOMMENDED.
Work Hygienic Practices:WASH WITH SOAP AND WATER, REMOVE CONTAMINATED
CLOTHING. SHOWER DAILY AND CHANGE CLOTHES INCLUDING UNDERGARMENTS.
Supplemental Safety and Health
FIRE FIGHT PROC: FOG NOZZLES FOR WATER IS RECOMMENDED. EXPLO HAZ: OF
HEAT. EMPTY CNTNRS MAY EXPLODE DUE TO RESIDUES. OBSERVE THIS MSDS
FOR EMPTIED CNTNR HANDLING. ALL METAL CNTNRS MUST BE GROUNDED &/B
ONDED DURING LIQ TRANSFER. HLTH HAZ: EYES; IRRIT OF EYES, WATERING,
BLURRED VISION. SKIN ABSORB: SEV IRRIT (SEE ING 4)

HCC:F4
Boiling Pt:B.P. Text:314F,157C
Vapor Pres:SEE ING 1
Vapor Density:HVR/AIR
Spec Gravity:1.1
Evaporation Rate & Reference:SLOWER THAN ETHER
Appearance and Odor:VISCOUS LIQUID WITH MINERAL SPIRITS ODOR.

Stability Indicator/Materials to Avoid:YES
AVOID STRONG OXIDIZING AGENTS, ACIDS AND BASES.
Stability Condition to Avoid:STORE AWAY FROM HEAT, ELECTRICAL EQUIP,
SPKS, OPEN FLAME.
Hazardous Decomposition Products:CARBON DIOXIDE, CARBON MONOXIDE, OTHER
OXIDES, TOXIC FUMES AND SMOKE.

Waste Disposal Methods:DISPOSE OF I/A/W FEDERAL, LOCAL AND STATE
REGULATIONS.

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of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.